Dear Lydia,
I'm sorry to see that the system doesn't start anymore.
There are two options to fix this:
1 If you can lose the data
1.1 uninstall Postgres
1.2 install it again.
**NOTE: all the data added to Calc will be lost**
2 If you cannot lose the data
2.1 Open PgAdmin
2.2 open the public.workspace table and take note of the workspace id you can remove
2.3 open a query editor and run an SQL command to delete the workspace: delete from public.workspace where id = WRITE_THE_ID
Please, let me know if you need more information.
Thank you
Mino